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Smart Nanomaterials from Metallo-Supramolecular Block-Copolymers. Design of Micellar Gels and Nanoporours Thin Films from Metallo-Supramolecular Block Copolymers
В наличии
Местонахождение: Алматы | Состояние экземпляра: новый |
Бумажная
версия
версия
Автор: Clement Mugemana
ISBN: 9783659634451
Год издания: 2015
Формат книги: 60×90/16 (145×215 мм)
Количество страниц: 276
Издательство: LAP LAMBERT Academic Publishing
Цена: 51693 тг
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Аннотация: The field of metallo-supramolecular block copolymers has recently become an intensive research area, as the system combines the self-assembly behaviour of block copolymers and coordination chemistry. The main goal of this thesis is the design of new smart nanomaterials from metallo-supramolecular block copolymers containing a stimuli responsive junction based on metal-terpyridine complex. A hierarchical self-assembly of the block copolymer end-capped with a terpyridine ligand in diluted and concentrated regime is described. The addition of metal ions to the micellar solution led to the formation flower-like micelles, while in concentrated regime a micellar gel exhibiting self-healing properties was triggered. The last part describes the design of thin films prepared from metallo-supramolecular block copolymers containing two immiscible blocks tethered by a stimuli responsive junction based on Nickel(II) bis-terpyridine complex. Nanoporous thin films were subsequently obtained simply by cleaving the complex located at the junction.
Ключевые слова: Block copolymers, micelles, Self-assembly, polymer gels, nanotechnology, rheology, thin films, SANS, self-healing.